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Following a brief review of the light-driven reactions in photosynthetic membranes, two questions are addressed. (1) Why is the first charge separation reaction in photosynthetic reaction centers so f...
The properties of photosynthetic reaction centers which make them interesting for technological applications are reviewed. Protein engineering has been used to systematically modify the oxidation pote...
Absorption and electro-absorption (Stark effect) spectra of polycrystalline and lyophillized samples of pheophorbides and bacteriopheophorbides have been measured in order to obtain information on the...
Photochemical hole burning has been observed at 1.5 K in bacteriorhodopsin (bR) and bovine rhodopsin at wavelengths spanning their lowest energy electronic absorption bands. Hole widths were approxima...
Rapid-flow resonance Raman vibrational spectra of bacterial photosynthetic reaction centers from the R-26 mutant of Rhodobacter sphaeroides have been obtained by using excitation wavelengths (810-910 ...
Electron-transfer reactions are expected to be particularly sensitive to externally applied electric fields because of the presence of charge-separated, dipolar states, and the effects of the field on...
Many experimental and theoretical approaches have been developed to characterize the chemical and physical properties of mixed-valence complexes. These molecules may possess metals in differing oxidat...
The effect of an applied electric field on the kinetics of the initial picosecond electron-transfer reaction in Rb. sphaeroides reaction centers has been measured in isotropic samples at 77 K. The net...
Site-directed mutagenesis is becoming a very important technique in the study of photosynthetic reaction center structure-function relationships. However, there are certain disadvantages associated wi...
The solution conformation of three related DNA hairpins, each with five bases in the loop, is investigated by proton and phosphorus 2D NMR methods. The sequences of the three oligomers are d(CGCGTTGTT...
The metal-to-ligand charge-transfer (MLCT) states of Ru- (diimine)32+and related complexes have been the subject of intense interest over the past 20 years in an effort to understand and potentially t...
The change in absorbance (hole spectrum) of the primary electron donor (P870) in bacterial photosynthetic reaction centers has been studied at 1.5-2.1 K following narrow-band excitation at several wav...

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