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Kinetics of Polymerization of 2-Hydroxyethylmethacrylate Initiated by a Titanium(III)-Dimethylglyoxime Redox System
Poly[2-hydoxyethylmethacrylate] Cyclic Voltammetry and Titanium(III)-Dimethylglyoxime
2010/4/21
Kinetics of Polymerization of 2-Hydroxyethylmethacrylate Initiated by a Titanium(III)-Dimethylglyoxime Redox System.
Thermal Decomposition Kinetics of Anilino-p-chlorophenylglyoxime Complexes of Cobalt (II), Nickel (II) and Copper (II)
Anilino-p-chlorophenylglyoxime Cu(II)-, Ni(II)- and Co(II)-complexes Thermal behaviour Thermal decomposition kinetic Pyrolysis DTA/TG/DTG
2010/4/21
The Co(II), Ni(II) and Cu(II) complexes of anilino-p-chlorophenylglyoxime were synthesised. The thermal behaviour of all complexes was studied by DTA and TG. It was found that pyrolytic decomposition ...
Base Hydrolysis Kinetics of Cobalt(III) Spiro-Octaamine Dimer
Base Hydrolysis Kinetics Cobalt
2010/4/22
The preparation and characterisation of a cobalt (III) complex of octaaza ligand, 5, 5'-bis(4-amino-2-azabutyl)-1,9-diamino-3,7-diazanonane (octaam) is described. The base hydrolysis kinetics of bis c...
Synthesis, Spectral and Thermal Degradation Kinetics of Divalent Cadmium Complexes of Dothiepine and Diphenhydramine
Spectral Thermal Degradation Kinetics Dothiepine Diphenhydramine
2010/4/22
Cadmium(II) complexes with 3-(6H-dibenzo[b,e] thiepin-11-ylidene) propyl dimethyl amine chloride (dot) and 2-diphenyl methoxy--N,N-dimethylamine hydrochloride (dp) were synthesised and characterised b...
The Kinetics and Mechanism of Oxidation of Vanillin by Diperiodatonickelate(IV) in Aqueous Alkaline Medium
Oxidation Vanillin Kinetics DPN
2010/4/22
The title reaction was investigated in aqueous alkaline medium. A first order dependence in diperiodatonickelate (IV) (DPN) and an apparent fractional order in both vanillin and alkali were obtained. ...
Direct measurements of memory effects in single-molecule kinetics
Direct measurements memory effects single-molecule kinetics
2014/9/24
Statistics and correlations of single-molecule sequences of modulated reactions are explicitly evaluated in the stochastic rate representation. The memory function, introduced through the Gaussian app...
The Influence of Transition Metal Ions on the Kinetics of Ascorbic Acid Oxidation by Methylene Blue in Strongly Acidic Media
The Influence of Transition Metal Ions the Kinetics of Ascorbic Acid Oxidation Methylene Blue
2010/4/22
The kinetics of the oxidation of L-ascorbic acid (H2 A) by methylene blue was investigated in strongly acidic media over the temperature range 22-40 oC. The kinetic studies were carried out as a funct...
Thermogravimetric Investigation of the Dehydration Kinetics of KSF, K10 and Turkish Bentonite
Dehydration kinetics Bentonite KSF K10 Ozawa method Coats-Redfern method
2010/4/23
The kinetic parameters for the dehydration of bentonite from Turkey, KSF and K10 were determined by using dynamic TG techniques. The Ozawa method is better for the dehydration of the clay samples than...
Spectral analysis of electron transfer kinetics. II
Spectral analysis electron transfer kinetics
2014/9/24
Electron transfer processes in Debye solvents are studied using a spectral analysis method recently proposed. Spectral structure of a nonadiabatic two-state diffusion equation is investigated to revea...
Reaction Mechanism and Kinetics of Aqueous Solutions of 2-Amino -2 Methyl-1,3- Propanediol and Carbonyl Sulphide
Reaction Mechanism Kinetics of Aqueous Solutions 2-Amino -2 Methyl-1,3- Propanediol Carbonyl Sulphide
2010/6/27
The mechanism and kinetics of the reaction between aqueous solutions of COS and a sterically hindered primary amine, 2-amino-2-methyl-1,3-propanediol (AMPD), were investigated at 288-303 K using a sto...
Two-Event Echos in Single-Molecule Kinetics: A Signature of Conformational Fluctuations
Two-Event Echoes Single-Molecule Kinetics A Signature of Conformational Fluctuations
2014/9/24
The relationship between event-averaged measurements and ensemble averaged measurements can be clarified by averaging along single-molecule trajectories. As a result, phenomenological chemical kinetic...
Kinetics and Thermodynamics of Oil Extraction from Sun ower Seeds in the Presence of Aqueous Acidic
Hexane kinetics oil extraction sulfuric acid sunflower seed thermodynamics
2010/6/27
Oil extraction was performed in aqueous HCl, H2SO4 and H3PO4 solutions with n-hexane (C6H14) at 30, 40, 50 and 60 oC using 10 gr of sunflower seeds over 1 h with 10-min. sampling intervals. The optimu...
Event-averaged measurements of single-molecule kinetics
Event-averaged measurements single-molecule kinetics
2014/9/24
A modulated N-conformational-channel reactive system is used to model the recent single-molecule enzymatic experiw .x ment Science 282 1998 1877 . Kinetic analysis of the model system clearly demonst...
Spectral analysis of electron transfer kinetics. I. Symmetric reactions
Spectral analysis electron transfer kinetics Asymmetric reactions
2014/9/24
A spectral analysis method is proposed to characterize multiple time scales in electron transfer processes, including vibrational relaxation, electronic coherence, activated curve crossing, or barrier...
Polarographic Studies on the Kinetics of the Electrode Reaction of 4-Benzoyl-1,5 Diphenyl Pyrazole-3-Carboxylic Acid
Polarographic Studies the Kinetics of the Electrode Reaction 4-Benzoyl-1,5 Diphenyl Pyrazole-3-Carboxylic Acid
2010/6/30
The polarographic behavior of 4-Benzoyl-1,5 diphenyl pyrazole-3- Carboxylic acid (BDPPCA) in aqueous ethanol solution (76 % v/v) at 25oC was studied as a function of pH using Mcl buffer solution. One ...